Abstract text: Great interest centres on novel enzyme sources for biomass valorisation. Phasmid insects are potentially such sources,* harbouring genes for cellulases, hemicellulases and pectinases. However, their ‘cellulase’ activity had been mainly assayed on carboxymethylcellulose (CMC), an artificial soluble substrate, which differs fundamentally from native semicrystalline cellulose. We tested whether conclusions based on CMC assays are applicable to insects feeding on leaves containing native cellulose and wall-bound matrix polysaccharides.
We quantified cellulose, pectin and hemicelluloses in alcohol-insoluble residues from privet (Ligustrum ovalifolium) leaves and from the corresponding frass (faeces) egested by the stick-insect Carausius morosus.
Approximately 65% of leaf wall-matrix material (homogalacturonan, rhamnogalacturonan-I, heteroxylans and xyloglucan) was ‘utilised’ (i.e., not egested) by live stick insects. However, in contrast to earlier claims, the phasmids utilised only 6% of the leaf cellulose.
In conclusion, Carausius morosus obtains >80% of its utilisable carbohydrate from pectin and hemicelluloses, ~15% from free sugars, and only ~5% from cellulose. Therefore, previous reports of high ‘cellulase’ activity in phasmids, based on genomics and CMC assays [1], cannot be directly applied to native cell-wall cellulose. Utilisation of wall-bound polysaccharides is the only realistic indicator of biomass valorisation.
*Reference: Shelomi et al., 2016. Insect Biochem Mol Biol 71: 1-11.